| dc.contributor.author | Tyunina, M. | |
| dc.contributor.author | Rusevich, Leonid L. | |
| dc.contributor.author | Savinov, M. | |
| dc.contributor.author | Kotomin, Eugene A. | |
| dc.contributor.author | Dejneka, A. | |
| dc.date.accessioned | 2024-02-09T10:03:36Z | |
| dc.date.available | 2024-02-09T10:03:36Z | |
| dc.date.issued | 2023 | |
| dc.identifier.issn | 2050-7526 | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2023/tc/d3tc03757f | |
| dc.identifier.uri | https://dspace.lu.lv/dspace/handle/7/65397 | |
| dc.description | The authors wish to thank T. Kocourek (PLD) and O. Pacherova (XRD). The work was partly supported by the Czech Science Foundation (Grant No. 22-10832S) (MT), the European Structural and Investment Funds and the Ministry of Education, Youth and Sports of the Czech Republic through Programme ‘‘Research, Development and Education’’ (Project No. SOLID21 – CZ.02.1.01/0.0/0.0/16_019/0000760) (MT, AD), and the Czech Academy of Sciences through the program Strategy AV21‘‘Breakthrough technologies for the future – sensing, digitization, artificial intelligence and quantum technologies’’ (MT, MS, AD). The financial support of M-ERA-NET HetCat project is acknowledged by LR and EK. The Institute of Solid State Physics, University of Latvia (Latvia) as the Centre of Excellence has received funding from the European Union’s Horizon 2020 Frame-work Programme H2020-WIDESPREAD01-2016-2017- Teaming Phase2 under grant agreement No. 739508, project CAMART2. The computer resources were provided by the Stuttgart Supercomputing Center (project DEFTD 12939) and Latvian Super cluster (LASC). | en_US |
| dc.description.abstract | Technologically important high-permittivity dielectrics are often achieved using cationic engineering of ABO3-type perovskite para(ferro)electrics. Here, we experimentally and theoretically explore the potential of less conventional anionic engineering in ABO3 dielectrics. We demonstrate that in an archetypal representative SrTiO3, nitrogen substitution can occur on two distinct oxygen atomic sites, reduce crystal symmetry, and lead to significant changes in the patterns and frequencies of lattice vibrations. These phonon transformations diminish permittivity, whereas contribution from nitrogen-induced nanoregions can raise it. The effects of nitrogen are found to be especially strong in epitaxial films. We anticipate that the revealed phenomena may be relevant for a broad class of high-permittivity perovskite oxides. --//-- This is an open-access article: M. Tyunina, L.L. Rusevich, M. Savinov, E.A. Kotomin, A. Dejneka. Dielectric behaviour of nitrogen doped perovskite SrTiO3-δNδ films. J. Mater. Chem. C, 2023, 11, pp. 16689–16698. DOI: 10.1039/d3tc03757f published under the CC BY-NC licence. | en_US |
| dc.description.sponsorship | Czech Science Foundation (Grant No. 22-10832S); European Structural and Investment Funds and the Ministry of Education, Youth and Sports of the Czech Republic (Project No. SOLID21 – CZ.02.1.01/0.0/0.0/16_019/0000760); Czech Academy of Sciences through the program Strategy AV21; M-ERA-NET HetCat project; The Institute of Solid State Physics, University of Latvia (Latvia) as the Centre of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD01-2016-2017- Teaming Phase2 under grant agreement No. 739508, project CAMART2. | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.relation | info:eu-repo/grantAgreement/EC/H2020/739508/EU/Centre of Advanced Material Research and Technology Transfer/CAMART² | en_US |
| dc.relation.ispartofseries | Journal of Materials Chemistry C;11, 16689 | |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Research Subject Categories::NATURAL SCIENCES::Physics | en_US |
| dc.title | Dielectric behaviour of nitrogen doped perovskite SrTiO3dNd films | en_US |
| dc.type | info:eu-repo/semantics/article | en_US |
| dc.identifier.doi | 10.1039/d3tc03757f | |
